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1

The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis

Amy B. Dounay, Larry E. Overman

Journal:

Year:

2003

File:

PDF, 51 KB

2003

2

Asymmetric Total Syntheses of (-)- and (+)-Strychnine and the Wieland-Gumlich Aldehyde

Knight, Steven D., Overman, Larry E., Pairaudeau, Garry

Journal:

Journal of the American Chemical Society

Year:

1995

Language:

english

File:

PDF, 2.21 MB

english, 1995

3

Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms

Büschleb, Martin, Dorich, Stéphane, Hanessian, Stephen, Tao, Daniel, Schenthal, Kyle B., Overman, Larry E.

Journal:

Angewandte Chemie International Edition

Year:

2016

Language:

english

File:

PDF, 26.37 MB

english, 2016

4

Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts

Cannon, Jeffrey S., Overman, Larry E.

Journal:

Accounts of Chemical Research

Year:

2016

Language:

english

File:

PDF, 2.25 MB

english, 2016

5

Total Synthesis of (−)-Crinine. Use of Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclizations for the Synthesis of Enantiomerically Pure Amaryllidaceae Alkaloids

Larry E. Overman, Soji Sugai

Journal:

Helvetica Chimica Acta

Year:

1985

Language:

english

File:

PDF, 350 KB

english, 1985

6

Molecular rearrangements in the construction of complex molecules

Larry E. Overman

Journal:

Year:

2009

Language:

english

File:

PDF, 1.02 MB

english, 2009

7

Kein Ende für Totalsynthesen von Strychnin in Sicht? Lektionen für Strategien und Methoden in der Totalsynthese

Jeffrey S. Cannon, Prof. Dr. Larry E. Overman

Journal:

Angewandte Chemie

Year:

2012

Language:

german

File:

PDF, 1.85 MB

german, 2012

8

A General Strategy for the Synthesis of Cladiellin Diterpenes: Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (Deacetoxyalcyonin Acetate), Cladiell-11-ene-3,6,7-triol, Sclerophytin A, and the Initially Purported Structure of Sclerophytin A

MacMillan, David W. C., Overman, Larry E., Pennington, Lewis D.

Journal:

Journal of the American Chemical Society

Year:

2001

Language:

english

File:

PDF, 395 KB

english, 2001

9

First total synthesis of Lycopodium alkaloids of the magellanane group. Enantioselective total syntheses of (-)-magellanine and (+)-magellaninone

Hirst, Gavin C., Johnson, Theodore O., Overman, Larry E.

Journal:

Journal of the American Chemical Society

Year:

1993

Language:

english

File:

PDF, 252 KB

english, 1993

10

Preparation of eight-membered cyclic ethers by Lewis acid promoted acetal-alkene cyclizations

Blumenkopf, Todd A., Bratz, Matthias, Castaneda, Armando, Look, Gary C., Overman, Larry E., Rodriguez, Domingo, Thompson, Andrew S.

Journal:

Journal of the American Chemical Society

Year:

1990

Language:

english

File:

PDF, 1.82 MB

english, 1990

11

Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene

MacMillan, David W. C., Overman, Larry E.

Journal:

Journal of the American Chemical Society

Year:

1995

Language:

english

File:

PDF, 785 KB

english, 1995

12

Organic Reactions || The Aza-Cope/Mannich Reaction

Overman, Larry E.

Year:

2004

Language:

english

File:

PDF, 1.59 MB

english, 2004

13

Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of ( Z )-α,β-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Intermediates

Ashimori, Atsuyuki, Bachand, Benoit, Calter, Michael A., Govek, Steven P., Overman, Larry E., Poon, Daniel J.

Journal:

Journal of the American Chemical Society

Year:

1998

Language:

english

File:

PDF, 319 KB

english, 1998

14

Scope and Facial Selectivity of the Prins-Pinacol Synthesis of Attached Rings

Overman, Larry E., Velthuisen, Emile J.

Journal:

Journal of Organic Chemistry

Year:

2006

Language:

english

File:

PDF, 326 KB

english, 2006

15

The insulin secretory action of novel polycyclic guanidines: Discovery through open innovation phenotypic screening, and exploration of structure–activity relationships

Shaghafi, Michael B., Barrett, David G., Willard, Francis S., Overman, Larry E.

Journal:

Bioorganic & Medicinal Chemistry Letters

Year:

2014

Language:

english

File:

PDF, 605 KB

english, 2014

16

Enantioselective Total Synthesis of Hispidospermidin

Overman, Larry E., Tomasi, Adam L.

Journal:

Journal of the American Chemical Society

Year:

1998

Language:

english

File:

PDF, 45 KB

english, 1998

17

Strategien für die Synthese von Naturstoffen mit benachbarten stereogenen quartären Kohlenstoffatomen

Büschleb, Martin, Dorich, Stéphane, Hanessian, Stephen, Tao, Daniel, Schenthal, Kyle B., Overman, Larry E.

Journal:

Angewandte Chemie

Year:

2016

Language:

german

File:

PDF, 26.37 MB

german, 2016

18

Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization Cross-Coupling Cascade

Overman, Larry E., Weires, Nicholas A., Slutskyy, Yuriy

Journal:

Angewandte Chemie International Edition

Year:

2019

Language:

english

File:

PDF, 1.26 MB

english, 2019

19

Enantioselective Total Synthesis of Macfarlandin C, a Spongian Diterpenoid Harboring a Concave-Substituted cis-Dioxabicyclo[3.3.0]octanone Fragment

Overman, Larry E., Allred, Tyler K., Dieskau, André P., Zhao, Peng, Lackner, Gregory L.

Journal:

Angewandte Chemie International Edition

Year:

2020

Language:

english

File:

PDF, 1.41 MB

english, 2020

20

Totalsynthese von (±)-Gelsemin

Andrew Madin, Christopher J. O'Donnell, Taeboem Oh, David W. Old, Larry E. Overman, Matthew J. Sharp

Journal:

Angewandte Chemie

Year:

1999

Language:

german

File:

PDF, 108 KB

german, 1999

21

Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and meso-Chimonanthine

Larry E. Overman, Jay F. Larrow, Brian A. Stearns, Jennifer M. Vance

Journal:

Angewandte Chemie

Year:

2000

Language:

english

File:

PDF, 95 KB

english, 2000

22

Total Synthesis of (±)-Gelsemine

Andrew Madin, Christopher J. O'Donnell, Taeboem Oh, David W. Old, Larry E. Overman, Matthew J. Sharp

Journal:

Angewandte Chemie International Edition

Year:

1999

Language:

english

File:

PDF, 116 KB

english, 1999

23

Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and meso-Chimonanthine

Larry E. Overman, Jay F. Larrow, Brian A. Stearns, Jennifer M. Vance

Journal:

Angewandte Chemie International Edition

Year:

2000

Language:

english

File:

PDF, 95 KB

english, 2000

24

Totalsynthese von (−)-Spirotryprostatin B und drei Stereoisomeren

Larry E. Overman, Mark D. Rosen

Journal:

Angewandte Chemie

Year:

2000

Language:

german

File:

PDF, 107 KB

german, 2000

25

Vereitelte β-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion

Martin Oestreich, Philip R. Dennison, Jeremy J. Kodanko, Larry E. Overman

Journal:

Angewandte Chemie

Year:

2001

Language:

german

File:

PDF, 127 KB

german, 2001

26

Diastereoselective Lithiation of (η6-Arene)dicarbonyltriphenylphosphane Chromium(0) Oxazoline Complexes—Direct Preparation of Enantiopure Complexes Having Planar Chiral Fragments of Either Configuration

Larry E. Overman, Carolyn E. Owen, G. Greg Zipp

Journal:

Angewandte Chemie

Year:

2002

Language:

english

File:

PDF, 97 KB

english, 2002

27

Total Synthesis of (−)-Spirotryprostatin B and Three Stereoisomers

Larry E. Overman, Mark D. Rosen

Journal:

Angewandte Chemie International Edition

Year:

2000

Language:

english

File:

PDF, 102 KB

english, 2000

28

Thwarting β-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction

Martin Oestreich, Philip R. Dennison, Jeremy J. Kodanko, Larry E. Overman

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 102 KB

english, 2001

29

Diastereoselective Lithiation of (η6-Arene)dicarbonyltriphenylphosphane Chromium(0) Oxazoline Complexes—Direct Preparation of Enantiopure Complexes Having Planar Chiral Fragments of Either Configuration

Larry E. Overman, Carolyn E. Owen, G. Greg Zipp

Journal:

Angewandte Chemie International Edition

Year:

2002

Language:

english

File:

PDF, 97 KB

english, 2002

30

Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols

Angela C. Olson, Larry E. Overman, Helen F. Sneddon, Joseph W. Ziller

Journal:

Advanced Synthesis & Catalysis

Year:

2009

Language:

english

File:

PDF, 274 KB

english, 2009

31

Quecksilber(II)- und Palladium(II)-katalysierte [3.3]-sigmatrope Umlagerungen

Prof. Dr. Larry E. Overman

Journal:

Angewandte Chemie

Year:

1984

File:

PDF, 837 KB

1984

32

Asymmetrische Heck-Reaktionen über neutrale Intermediate: Verstärkung der Enantioselektion durch Halogenid-Additive und Einblicke in den Mechanismus

Prof. Larry E. Overman, Daniel J. Poon

Journal:

Angewandte Chemie

Year:

1997

File:

PDF, 390 KB

1997

33

Enantioselective Total Syntheses of the Cyclotryptamine Alkaloids Hodgkinsine and Hodgkinsine B

Jeremy J. Kodanko, Larry E. Overman

Journal:

Angewandte Chemie

Year:

2003

Language:

english

File:

PDF, 115 KB

english, 2003

34

Enantioselective Total Synthesis of the Cyclotryptamine Alkaloid Idiospermuline

Larry E. Overman, Emily A. Peterson

Journal:

Angewandte Chemie

Year:

2003

Language:

english

File:

PDF, 111 KB

english, 2003

35

Total Synthesis of (−)-Sarain A

Neil K. Garg, Sheldon Hiebert, Larry E. Overman

Journal:

Angewandte Chemie

Year:

2006

Language:

english

File:

PDF, 136 KB

english, 2006

36

Totalsynthese komplexer Cyclotryptaminalkaloide: stereokontrollierter Aufbau quartärer Kohlenstoffstereozentren

Alan Steven, Larry E. Overman

Journal:

Angewandte Chemie

Year:

2007

Language:

german

File:

PDF, 1.29 MB

german, 2007

37

Mercury(II)- and Palladium(II)-Catalyzed [3,3]-Sigmatropic Rearrangements [New Synthetic Methods (46)]

Prof. Larry E. Overman

Journal:

Angewandte Chemie International Edition

Year:

1984

Language:

english

File:

PDF, 767 KB

english, 1984

38

Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights

Prof. Larry E. Overman, Daniel J. Poon

Journal:

Angewandte Chemie International Edition

Year:

1997

Language:

english

File:

PDF, 547 KB

english, 1997

39

Enantioselective Total Syntheses of the Cyclotryptamine Alkaloids Hodgkinsine and Hodgkinsine B

Jeremy J. Kodanko, Larry E. Overman

Journal:

Angewandte Chemie International Edition

Year:

2003

Language:

english

File:

PDF, 116 KB

english, 2003

40

Enantioselective Total Synthesis of the Cyclotryptamine Alkaloid Idiospermuline

Larry E. Overman, Emily A. Peterson

Journal:

Angewandte Chemie International Edition

Year:

2003

Language:

english

File:

PDF, 112 KB

english, 2003

41

Total Synthesis of (−)-Sarain A

Neil K. Garg, Sheldon Hiebert, Larry E. Overman

Journal:

Angewandte Chemie International Edition

Year:

2006

Language:

english

File:

PDF, 136 KB

english, 2006

42

Total Synthesis of Complex Cyclotryptamine Alkaloids: Stereocontrolled Construction of Quaternary Carbon Stereocenters

Alan Steven, Larry E. Overman

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 1.01 MB

english, 2007

43

ChemInform Abstract: Planar-Chiral Cyclopalladated Ferrocenyl Amines and Imines as Enantioselective Catalysts for Allylic Imidate Rearrangements.

Frederick Cohen, Larry E. Overman

Journal:

Year:

1999

File:

PDF, 29 KB

1999

44

ChemInform Abstract: Asymmetric Construction of the Diazatricyclic Core of the Marine Alkaloids Sarains A—C.

Robert Downham, Fay W. Ng, Larry E. Overman

Journal:

Year:

1999

File:

PDF, 34 KB

1999

45

ChemInform Abstract: Total Synthesis of (+)-Aloperine. Use of a Nitrogen-Bound Silicon Tether in an Intramolecular Diels—Alder Reaction.

Arthur D. Brosius, Larry E. Overman, Lothar Schwink

Journal:

Year:

1999

File:

PDF, 37 KB

1999

46

ChemInform Abstract: Stereocontrolled Synthesis of Trisubstituted Tetrahydropyrans.

Mary J. Cloninger, Larry E. Overman

Journal:

Year:

1999

File:

PDF, 28 KB

1999

47

ChemInform Abstract: Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B.

Alison S. Franklin, Sylvie K. Ly, Gilbert H. Mackin, Larry E. Overman, A. J. Shaka

Journal:

Year:

1999

File:

PDF, 25 KB

1999

48

ChemInform Abstract: High Enantioselection in the Rearrangement of Allylic Imidates with Ferrocenyl Oxazoline Catalysts.

Yariv Donde, Larry E. Overman

Journal:

Year:

1999

File:

PDF, 33 KB

1999

49

ChemInform Abstract: Palladium Catalyzed Enantioselective Rearrangement of Allylic Imidates to Allylic Amides

T. Keith Hollis, Larry E. Overman

Journal:

Year:

1999

File:

PDF, 24 KB

1999

50

ChemInform Abstract: Tuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis- or trans-1-Oxo- and 1-Iminohexahydropyrrolo[1,2-c]pyrimidines.

Andrew I. McDonald, Larry E. Overman

Journal:

Year:

1999

File:

PDF, 32 KB

1999